FIGURE 4.27 Homolytic cleavage of the Fe (III) hydroperoxy complex.

activity because it is responsible for the preorganization and stabilization of a compact conformation implicated in DNA cleavage.74

Bleomycins are large molecules (ca. 1.5 kDa) and therefore they are probably unable to diffuse through cell membranes. After administration, it has been proposed that they bind rapidly and irreversibly to Cu (II) in plasma. It is believed that

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