S

S-glutathiolation, see Protein kinase C Single-crystal ultraviolet-visible microspectrophotometry copper-containing amine oxidase catalytic intermediate observations, 315 crystal preparation, 314-315 crystal alignment chromophore nonrandomness in crystals, 308-309

path length inaccuracy reduction, 309-310 prism effects, 309 crystal mounting kinetic experiments, 310-313 spectra aquisition experiments, 306-308 instrumentation, 306, 317-318 prospects, 318

rationale for redox state determination,

301-302, 305-306 X-ray effects

Compton scattering, 304 elastic scattering, 304 photoelectric effect and satellite processes, 304

redox center oxidation state, 302 secondary cascade processes in radiation damage, 305 Single-nucleotide polymorphism DNA intercalator assays of DNA mismatch detection based on electronic destabilization chronocoulometry, 522 cyclic voltammetry, 522 efficacy of electron transfer, 516, 518 electrode preparation, 516, 521-522 methylene blue reduction of Fe(CN)g~, 518

principles, 515-516 thiol-modified DNA construction, 519, 521

detection based on thermodynamic and kinetic destabilization metallointercalators, 508-509 photolysis, 513

plasmid mismatch studies, 509, 511, 514-515

[Rh(bpy)2chrysi]Cl synthesis, 511-512 sequencing, 514 overview, 506-507 repair, 506

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